Tube od surfaces experience thermal fatigue stress cycles which can occur from normal shedding of slag, sootblowing, or from cyclic operation of the boiler. Carbon steel in caustic service corrosion engineering. Protecting your steam turbine from corrosion power. Corrosion of this type generally results from fouled heat transfer surfaces and the presence of an active corrodent sodium hydroxide in the boiler water6,7. Sodium hydroxide solutions are used in a variety of. An experimental program on stress corrosion cracking scc aimed at the development of a quantitative model for predicting the behavior of inconel 600 tubing in high temperature water is currently underway at brookhaven national laboratory bnl. For cscc to cause a failure, a number of factors and conditions must be present in the correct amounts. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at. Industrial experience on the caustic cracking of stainless. Learn vocabulary, terms, and more with flashcards, games, and other study tools.
Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Corrosion, stress corrosion cracking, and electrochemistry of. Although fatigue is a degradation mechanism that is second in importance to radiation. Stress corrosion cracking and hydrogen embrittlement of. Stress corrosion cracking international institute of. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic.
Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Similarly other specific stress corrosion cracking processes have acquired their own names. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Api rp 571 damage mechanisms affecting fixed equipment. For caustic stress corrosion cracking, what is the effect of temperature and concentration mechanisms. Stress corrosion cracking susceptibility of medium carbon steel in caustic and potash media a. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism. Cracking mechanism an overview sciencedirect topics. Potentiostatically controlled tests were conducted near the activepassive transition, using fracture mechanics testing techniques and fatigue precracked double cantilever beam specimens. Specialized corrosion doehdbk1015193 corrosion ch02 rev. Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion products including na 3 feo 3, na. Stress corrosion cracking of carbon steel in caustic.
Biological corrosion, bacterial corrosion, microbial corrosion. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the scc mechanisms for dss in caustic solutions were not known. Also, the fracturemechanics con cept of design assumes preexisting flaws in materials, although these may not be surface flaws that can become stress corrosion. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Michael j schofield bsc, msc, phd, mim, ceng, in plant engineers reference book second edition, 2002. Avoiding stress corrosion cracking of carbon low alloy and.
In an ideal world a stress corrosion cracking control strategy will start operating at the design stage, and will focus on the. Caustic embrittlement focuses on the stressed parts of the boiler, including cracks, bends, rivets and joints. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. A number of different corrosion mechanisms can ensue, one commonly found mechanism is caustic corrosion. Metalenvironment combinations susceptible to cracking are specific. Three basic mechanisms of stress corrosion cracking have been identified as. There is caustic stress corrosion cracking when carbon steel is exposed to concentrated caustic solution. This due to high concentration of the caustic soda added to the boiler water to control ph ph 9. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. The five categories of stainless steels and key features essential for stress corrosion cracking are introduced.
The mechanism of stress corrosion cracking is not well understood but it is believed to be caused by stress, corrosive environments and susceptible microstructures. Caustic stress corrosion cracking caustic embrittlement. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Explains caustic embrittlement, season cracking, hydrogen.
This mechanism has been extensively studied in stress corrosion cracking of alpha brass in ammoniacal environment and also proposed for caustic cracking of boiler steel. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. Mechanisms and modeling of stress corrosion cracking in. This study is to identify factors responsible for loss of production due to problems in plant and equipment. The design engineer may not always be fully aware of lhe possibility of brittle failures in fastener systems that could result from stress corrosion cracking scc or hydrogen stress cracking hsc. Caustic corrosion an overview sciencedirect topics. The mechanism is similar to that of chloride stress corrosion.
Nace sp0403 avoiding caustic stress corrosion cracking. Stresscorrosioncracking view from the penthouse the dnfm. Stress corrosion cracking, a very important topic of machine design. Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic. Cracking mechanisms in which corrosion is implicated include stress corrosion cracking, corrosion fatigue, hydrogeninduced cracking and liquid metal embrittlement. Although amines form a high ph solution and may cause scc, it is considered a different mechanism for the purposes of this standard and amine scc is not addressed. Evidence of intergranular attack iga in the absence of stress, together with dissolution kinetics, indicates that intergranular stress corrosion cracking igscc of ferritic steels in various environments is by a dissolution mechanism. Selection of stainless steels for handling sodium hydroxide. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms. Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic concentration. These alloys can however suffer from caustic stress corrosion cracking at caustic.
Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Mechanistic aspects of intergranular stress corrosion. May 06, 2014 stress corrosion cracking, a very important topic of machine design. The lead author outlined in the first half of the paper that during scheduled outages on two power generating units at his company, nondestructive testing ndt revealed stress corrosion cracking. In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal. So, lack of pwht will increase susceptibility, mostly from residual tensile stresses, and not just hardness. It becomes increasingly more corrosive with increasing temperature and concentration. Stresscorrosioncracking view from the penthouse the.
The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. Careful design and operation of caustic injection equipment is needed to. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Risk of stress corrosion cracking attack caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. The model is based on the idea of a straininduced rupture of the protective film, and so plastic strains play a main role in failure processes 52, 55. Residual sodium carbonate, which is used for the softening process, undergoes hydrolysis, forming sodium hydroxide at high pressures and temperatures. Carbon steel in caustic service corrosion engineering eng. As with other cracking mechanisms, there is a threshold stress level where cracking will not occur. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Corrosionpedia what is stress corrosion cracking scc. Then, the stress corrosion cracking mechanism for various materials in. Caustic stress corrosion cracking inspectioneering. The paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems.
Introduction in the united states currently there are approximately 104 operating. May 09, 2009 part 2 flow accelerated corrosion fac. This due to high concentration of the caustic soda added. The impact of scc on a material usually falls between dry cracking. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Austenitic stainless steels suffer from scc in chlorides, caustic, and. Most of those who own solid stainless steel equipment operating in the cui temperature range are likely to experience ecscc at some point. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved.
For cscc to cause a failure, a number of factors and conditions must. Stress corrosion cracking scc of type 316 stainless. Abstract the paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems. In practice, most cases have been attributed to caustic cracking and extreme care. Caustic embrittlement is also known as stress corrosion cracking. Due to power ated within these limits, no major stress ful concentrating mechanisms operative in corrosion cracking. Mechanisms of stress corrosion cracking and intergranular attack in alloy 600 in high temperature caustic. Im hoping to add to the contributions in this field of research by taking the time to archive notable events in my lab. Borode school of chemical and metallurgical engineering, faculty of engineering and the built. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Caustic scc is driven by tensile stress, susceptible material and concentration of caustic. Three different mechanisms involved in stress corrosion. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to.
Api rp 571, damage mechanisms affecting fixed equipment in the refining industry, third edition, is a recommended practice developed and published by the american petroleum institute api that provides an indepth look at over 60 different damage mechanisms. Scc is well known as the major mechanism of alloy 600 sg tubing failure occurring in the. Mechanisms of stresscorrosion cracking asm international. Caustic stress corrosion cracking creative engineers, inc. In order to have scc, three conditions must be satisfied. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking of inconel alloy 600 in high temperature wateran update. Austenitic stainless steels are better at resisting. Susceptibility to caustic scc is dependent on several variables, including alloy content, caustic concentration, temperature and stress level. Stress corrosion cracking of inconel alloy 600 in high. The most damaging forms of stress corrosion cracking in austenitic stainless steels are chloride and caustic stress corrosion cracking and cracking in high temperature, high pressure aqueous environments. This means that all environments do not cause scc on all of the alloys.
Stress corrosion cracking scc of type 304 stainless steel in 20n caustic solution was investigated in the presence of chromate ions, using the constant strain rate 10sup 710sup 5s technique. Stress corrosion cracking behavior of alloy 600 coupled to. Stress corrosion cracking scc hydrogen damage sulphur corrosion graphitization thermal fatigue waterside corrosion fatigue soot. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Environmental cracking season cracking caustic cracking caustic embrittlement stress corrosion cracking scc hydrogeninduced. As with other forms of stress corrosion cracking, caustic cracking will. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing. Stress corrosion cracking of duplex stainless steels in. External chloride stress corrosion cracking ecscc is a specific form of cui that occurs in austenitic stainless steels 300 series ss. Effect of temperature and some inhibitors on stress corrosion. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel.
Microstructural changes during fabrication processes affect the overall scc susceptibility of these steels in caustic. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. French metallurgists news letter page 1 of 7 stress corrosion cracking scc is a welldefined failure mechanism in metals. Thermal cycling, in addition to subjecting the material to cyclic stress, can initiate cracking of the less elastic external tube scales and expose the tube base material to repeated corrosion. Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion. Environmental cracking season cracking caustic cracking caustic embrittlement stress. It can lead to unexpected sudden failure of normally ductile metals. Stress corrosion cracking caustic embrittlement of super. The mechanism of scc is shown as a simple representation in figure 1. The design of industrial structures and components is usually based on tensile. Real components will typically contain defects and design. Intergranular stress corrosion cracking weld decay knifeline attack kla exfoliation layer corrosion stray current corrosion. Caustic corrosion caustic corrosion is referred to as caustic attack, caustic gouging, or ductile gouging.
Stainless steels are more resistant to general corrosion compared with carbon steel. Stress corrosion cracking behavior of nickel base alloys. Results confirmed that the chromate ions act as an oxidizing inhibitor and prevent caustic cracking. Caustic embrittlement was first used to describe the cracking of riveted mild steel boiler plates due to local deposition of concentrated hydroxide at temperatures of 200 to 250 o c 400 to 480 o f. Also, the fracturemechanics con cept of design assumes preexisting flaws in materials, although these may not be surface flaws that can become stresscorrosion. It was later known as stress corrosion cracking which is in turn replaced by caustic cracking.40 1503 60 818 1196 464 54 1401 945 517 133 594 219 875 253 1316 397 555 742 1427 201 601 920 605 926 252 579 1345 286 1325 628 165 431 541 902 631 1329 1351 278 779 846